Product ID:1,1,1-TRICHLOROETHANE, 9426
MSDS Date:06/09/1994
FSC:6810
NIIN:00N049511
MSDS Number: CBCFW

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865
US

Emergency Phone: 800-424-8802;800-424-9300(CHEMTREC)

Info Phone: 908-859-2151

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 90-100%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM;450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL,RAT) 4200 MG/KG.

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: <3%

OSHA PEL 100 PPM, S

ACGIH TLV: 25 PPM, S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BUTANE, 1,2-BUTOXY-; (1,2-BUTYLENE OXIDE) (SARA 313)

CAS: 106-88-7

RTECS: EK3675000

Fraction By Weight: <0.5%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G.,
EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING
USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
ACUTE: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:P-DIOXANE:IARC MONOGRAPHS, SUPP, VOL 7,
PG 201, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO
BE (SUPP DATA)
Effects of Overexposure:HLTH HAZ:INHAL:MAY CAUSE PULM EDEMA, HDCH,
NAUSEA, VOMITING, DIZZ, DROW, IRRIT OF UPPER RESP TRACT,
UNCONSCIOUSNESS. SKIN CONTACT:IRRIT, PROLONGED CONTACT MAY CAUSE
DERMATITIS. EYE CONTACT:IRRITATION. SKIN ABSORPTION:NONE
IDENTIFIED. INGEST:NAUSEA, VOMITING. CHRONIC:KIDNEY/LIVER DMG.
TARGET ORGANS:CNS, SKIN, EYES, CVS.
Medical Cond Aggravated by Exposure:LIVER DISORDERS, HEART DISORDERS,
SENSITIVE SKIN.

First Aid:INGEST:CALL MD. IF SWALLOWED, DO NOT INDUCE VOMITING.
INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTF RESP. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. PROMPT ACTION IS ESSENTIAL.
SKIN:FLUSH W/WATER FOR AT LEAST 15 MINUTES. EYES:IMMEDIATELY FLUSH
W/PLENTY OF WATER FOR AT LEAST 15 MINUTES.

Flash Point Method:CC
Lower Limits:7.5%
Upper Limits:15%
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE . NONE IDENTIFIED.

Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
STOP LEAK IF YOU CAN DO SO W/OUT RISK. USE WATER SPRAY TO REDUCE
VAPS. TAKE UP W/SAND OR OTHER NON-COMBUST ABSORB MATL & PLACE INTO
CNTNR FOR LATER DISP. FLUSH SPILL AREA W/WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. SUITABLE FOR
ANY GEN CHEM STOR AREA. KEEP AWAY FROM FOOD. CAUSES IRRIT. HARMFUL
IF SWALLOWED/INHALED. AVOID BRTHG VAPOR.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF HCL &/OR PHOSGENE . KEEP OUT OF REACH OF CHILDREN.
WARNING:1,1,1-TR ICHLOROETHANE IS A SUBSTANCE (SUPP DATA)

Respiratory Protection:NONE REQUIRED WHERE ADEQ VENT CNDTNS EXIST. IF
AIRBORNE CONC IS HIGH, A NIOSH/MSHA APPROVED CHEMICAL CARTRIDGE
RESP W/ORGANIC VAPOR CARTRIDGE IS REC. IF CONC EXCEEDS CAPACITY OF
CARTRIDGE RESP, A NIOS H/MSHA APPROVED SCBA IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS. VENT HOOD.
Protective Gloves:POLYVINYL ALCOHOL GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . UNIFORM, APRON ARE RECOMMENDED. LAB COAT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLAN OF CARCIN:CARCIN. ANIMAL:KIDNEY, LIVER. OTHER PREC:WHICH HARMS
PUBLIC HLTH & THE ENVIRON BY DESTROYING THE OZONE IN THE UPPER ATM.
AVOID CONT W/EYES, SKIN, CLTHG. USE W/ADEQ VENT. NOTE:WHEN HND LG
LIQ PRODS, SECONDARY PROT CNTNRS MUST BE USED FOR CARRYING.

Boiling Pt:B.P. Text:165F,74C
Melt/Freeze Pt:M.P/F.P Text:-27F,-33C
Vapor Pres:100 @ 20C
Vapor Density:4.6
Spec Gravity:1.32 (H*2O=1)
Evaporation Rate & Reference:12.8 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE (<0.1%)
Appearance and Odor:COLORLESS LIQUID; FAINT ETHER-LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
WATER, STRONG BASES, ALUMINUM, CHEMICALLY ACTIVE METALS, STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:MOISTURE, INSUFFICIENT INHIBITOR, HEAT,
FLAME, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE,
CARBON MONOXIDE.

Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE &
LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U226
(TOXIC WASTE).

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of Defense. The United States of America in no manner whatsoever,
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particular situation.